Vibrational calculations in formaldehyde: the CH stretch system
نویسندگان
چکیده
منابع مشابه
IR and FTMW-IR spectroscopy and vibrational relaxation pathways in the CH stretch region of CH3OH and CH3OD.
Infrared spectra of jet-cooled CH(3)OD and CH(3)OH in the CH stretch region are observed by coherence-converted population transfer Fourier transform microwave-infrared (CCPT-FTMW-IR) spectroscopy (E torsional species only) and by slit-jet single resonance spectroscopy (both A and E torsional species, CH(3)OH only). Twagirayezu et al. reported the analysis of ν(3) symmetric CH stretch region (2...
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Gas-phase fundamental and CH and CO overtone spectra (700-17 500 cm -I) of 2,2,2trideuteroacetaldehyde were recorded using FTIR and laser photoacoustic techniques. The Fermi resonance structure in the overtone spectra of the coupled CH stretching and in-plane CH bending vibrations is analyzed with a tridiagonal Hamiltonian, yielding a large effective coupling constant, I k ;bb I = 93 cm I, corr...
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We report measurement and analysis of the photodissociation spectrum of hydroxymethyl hydroperoxide (HOCH(2)OOH) and its partially deuterated analogue, HOCD(2)OOH, in the OH-stretching region. Spectra are obtained by Fourier transform infrared spectroscopy in the 1nu(OH) and 2nu(OH) regions, and by laser induced fluorescence detection of the OH fragment produced from dissociation of HOCH(2)OOH ...
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Formaldehyde in small quantities is commonly analyzed by spectrophotometric methods. One of the most-commonly used spectrophotometric techniques for this purpose is based on the reaction with chromotropic acid. Because of its simplicity, sensitivity, selectivity and its low cost, it is still widely used. Investigations for replacing the concentrated sulfuric acid with other acids or using more ...
متن کاملCH Stretching Region: Computational Modeling of Vibrational Optical Activity.
Most organic compounds provide vibrational spectra within the CH stretching region, yet the signal is difficult to interpret because of multiple difficulties in experiment and modeling. To better understand various factors involved, the ability of several harmonic and anharmonic computational approaches to describe these vibrations was explored for α-pinene, fenchone, and camphor as test compou...
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ژورنال
عنوان ژورنال: Open Chemistry
سال: 2011
ISSN: 2391-5420
DOI: 10.2478/s11532-011-0042-6